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- Measuring dispersion on the refractometer
- Gemstone resources in China
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Glass-filled rubies
Discriminating turquoise from its imitations
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(Follow this link for abstracts of past issues)
PRACTICAL APPLICATION FOR MEASURING GEMSTONE DISPERSION ON THE REFRACTOMETER
- Using the C - F solar spectral interval
Trevor Linton
Brisbane Queensland Australia
EXTENDED ABSTRACT
This paper will discuss techniques developed while researching practical
aspects for determining the apparent and true dispersion of gemstones using
a gemmological refractometer. Each gemstone has a distinct dispersion, since
dispersion is a property related to a variation in refractive index with a
change in wavelength.
Low-dispersion barium glass yields a colourless
refractometer glass that allows measurement of refractive index in deep blue
light below 500 run when used in association with the hemisphere or
hemicylinder prism refractometer to which the wide field eyepiece of the
Eickhorst SR/M refractometer has been attached. The Eichorst refractometer,
with a visually expanded scale, is the preferred instrument for measuring
dispersion because apparent refractive index can be measured at wavelengths
other than that of the standard sodium emission light source at 589.3 nm.
Accuracy, not available on sixty-degree exit prism refractometers, is
available for refractive index determinations at many wavelengths not
previously available on refractometers.
The choice of lighting techniques can improve the
accuracy of refractive index determinations when used in association with
appropriate sources of narrow bandwidth blue 486 run and red 656 nm
wavelengths. These measuring techniques, when combined with extrapolation of
a Rl-wavelength dispersion curve using Sellmeier's linear conversion,
permits the extrapolation of refractive indices at B (686.7 nm) and G (430.7
nm) wavelengths and allows comparisons of these data with values previously
published in the gemmological literature
This research suggests that existing B to G lists
for the dispersions of gemstones leave much to be desired with respect to
their accuracy. Dispersion at II-G interval was rarely measured. It was
extrapolated by various techniques that provide conflicting data. The B-G
interval for the measurement of dispersion that was adopted by gemmology
produced a larger value, but this is of no practical use to gemmologists.
A new list of values for the dispersions of
gemstones, measured at the CT (656.3 - 486.1 nm) interval with the
assistance of the gem refractometer, is presented in table 3 of this paper.
Measurements of dispersion, with the gemmologist's
refractometer, produces apparent dispersion. However, a means of converting
this to true dispersion, after extrapolation, can be achieved by Suhner's
technique of subtracting apparent dispersion from the sum of true plus
apparent dispersions.
GEMSTONE RESOURCES OF CHINA
Professor C.M. (Mimi) Ou Yang
Hong Kong Institute of Gemmology, Hong Kong
ABSTRACT
The Peoples' Republic of China has a large and ancient land mass that is
host to vast, largely untapped reserves of gemstones. In this paper the
author will briefly describe and illustrate the occurrences of gemstones
that are relatively common in China, before providing useful tabulation of
the occurrence of these and other gemstones in this historically ancient
country.
GLASS-FILLED RUBIES
- Clarity-enhanced rubies with glass-forming additives
Ted Themelis
Bangkok, Thailand
ABSTRACT
This paper described the filling of fractured rubies with lead, bismuth,
tantalum and other oxides-additives including chromophores. In December 2004
a series of experiments were performed at the author's gem treatment lab in
Bangkok, using various methodologies practiced commercially in Thailand. The
experiments showed that certain combination of metal oxides can effectively
fill surface reaching cavities in rubies at relatively low to mid range
temperatures of 900-1300 oC. Starting material consisted of rubies with
surface-reaching cracks. After treatment, the cracks were filled with the
clarity and overall appearance of these rubies being considerably improved.
The structure of most of these fillers is amorphous, thus these rubies may
be referred to as glass-filled rubies. In Thailand these
treated rubies are known as ruby-star or by their alternative name
pao-mai, meaning new burn in the Thai language. This treatment is easily
identified with a gemmological microscope; where characteristic inclusions
such as the 'flash-effect', irregular-shaped reflective platelets/voids,
'frosted' areas, gas 'bubbles' and other features are observed. Stability
and durability of the glass-filled rubies may be somewhat affected due to
recutting and polishing and jewellery repairs. Disclosure of this treatment
is mandatory, and their selling price in the market is relatively low.
USE OF IR-SPECTROSCOPY AND
DIFFRACTION TO DISCRIMINATE BETWEEN NATURAL, SYNTHETIC AND TREATED
TURQUOISE, AND ITS IMITATIONS
1Alessandro Pavese,
2Loredana
Prosperi,
3Monica
Dapiaggi
1Professor
of Mineralogy, Università degli Studi di Milano, Milano, Italy
2Gemmological
Laboratory, Instituto Gemmologico Italiano, Sesto San Giovanni, Italy
3Senior
Researcher, Dipartimento di Scienze della Terra, Università degli Studi di
Milano, Milano, Italy
ABSTRACT
This study aims at providing an overview, based on a statistically
significant number of samples, about the reliability of nondestructive IR
spectroscopy, combined in some cases with diffraction, to determine the
nature of turquoise specimens, be they natural, synthetic, treated, or its
imitations. A total of 94 samples (32 natural, 12 synthetic, 16 treated, 34
imitations) were analysed by infrared spectroscopy in the non-destructive
reflectance mode. Treated turquoise specimens were also studied in the IR
transmission mode. Non-destructive X-ray diffraction was been used to remove
ambiguities that IR spectroscopy was unable to resolve with respect to some
imitations.
Key-words: natural, synthetic and
treated turquoise; imitations; FTIR; Diffraction.
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